Abstract

The influence of some dyes on the photodegradation of a polyamidehydroxyurethane type polymer in aqueous solution has been studied. It has been found that, among the dyes used, only riboflavin sensitizes and accelerates the degradation of the polymer. It is proposed that under ultraviolet irradiation riboflavin undergoes photoreduction to lumichrome, which sensitizes the photodegradation of the polymer. It is also possible that the mechanism of photodegradation involves the participation of singlet oxygen.

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