Abstract

A photochemical method has been exploited for the synthesis of electrically conductive silver (Ag) nanowires in a polymer solution in the presence of negatively charged Au seed particles. The synthesis was completed within 8 min of UV-photoirradiation in ambient conditions. The nanowires were fabricated on a PVA template having an average diameter of 135 ± 20 nm and a length of 10–20 μm. The current–voltage ( I– V) characterization showed that the PVA–Ag nanowires were continuous, having Ohmic behavior with low contact resistance. Results indicate that the PVA acted as a reducing agent, stabilizing agent, and a template for the nucleation and growth of Ag nanowires. The Ag deposition was highly selective and on the PVA only. Our research indicated that the PVA–Ag nanowires might be useful as interconnects in nanoscale integrated circuitry, functional nanodevices, and in optoelectronics.

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