Abstract

Abstract A photocatalytic microreactor with immobilized TiO 2 layer was developed and the processes of degradation and reduction of organic compounds, and amine N -alkylation in microspace were examined. These model reactions proceeded very rapidly with considerably large photonic efficiencies. In contrast to the result in a batch reactor, we successfully observed N -alkylation reaction of benzylamine by using the microreactor with immobilized Pt-free TiO 2 as well as TiO 2 /Pt. These results suggest the feasibility of a catalytic microreaction system on organic photoreactions.

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