Abstract

The present study reports the synthesis of the Fe2O3/Cu2O nanocomposite via a facile hydrothermal route. The products were characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), high-resolution transmission electron microscopy (HR-TEM), energy dispersive spectroscopy (EDS) and Brunauer–Emmett–Teller (BET) techniques. The composition, morphology and structural features of the nanoparticles were found to be size-dependent due to the temperature response in the particular time log during hydrothermal synthesis. HR-TEM confirmed the formation of hexagonal rod-shaped bare Cu2O, rhombohedral-shaped Fe2O3 and composite assembly. Rhodamine-B (RB) and Janus green (JG) were chosen as model dyes for the degradation studies. Photocatalytic degradation of the dyes was deliberated by altering the catalyst and dye concentrations. The results showed that the Rhodamine-B (RB) and Janus green (JG) dyes were degraded within a short time span. The synthesized materials were found to be highly stable in the visible light-driven degradation of the dyes; showed antibacterial activity against E. coli, P. aeruginosa, Staph. aureus and B. subtilis; and exhibited less toxicity against the Musmusculus skin melanoma cells (B16-F10). The fusion of these advantages paves the way for further applications in energy conversion, biological applications as well as in environmental remediation.

Highlights

  • IntroductionInimitable properties and the assessment of interactions between nanomaterials and the biological system are essential.[28] In recent years, the cell line toxicity of human cell lines using several synthesized metal oxide is a more fascinating topic in understanding the relationship between nanoparticle– cell interactions.[29,30] The size, shape, and morphology of nanoparticles, play a vital role in mammalian cell culture medium, and the nanoparticle are much more toxic than the hydrothermally synthesized nanocomposite semiconductor.[31,32] In this experiment, we focus on exploiting and utilizing some multi-tasking facile materials with high photocatalytic activity and biological applications

  • Photocatalysis is a fascinating tool for energy conversion and environmental decontamination due to its conspicuous nature.[1]

  • The results showed that the Rhodamine-B (RB) and Janus green (JG) dyes were degraded within a short time span

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Summary

Introduction

Inimitable properties and the assessment of interactions between nanomaterials and the biological system are essential.[28] In recent years, the cell line toxicity of human cell lines using several synthesized metal oxide is a more fascinating topic in understanding the relationship between nanoparticle– cell interactions.[29,30] The size, shape, and morphology of nanoparticles, play a vital role in mammalian cell culture medium, and the nanoparticle are much more toxic than the hydrothermally synthesized nanocomposite semiconductor.[31,32] In this experiment, we focus on exploiting and utilizing some multi-tasking facile materials with high photocatalytic activity and biological applications. Fe2O3 burdened onto Cu2O and the nanocomposite was prepared by a facile method. The (p–n) hetero-junction nanocomposite was used for the effective degradation of organic pollutants; including Rhodamine-B (RB) and Janus green (JG), bacterial degradation and some additional biological screening applications

Hydrothermal preparation of Fe2O3
Photocatalytic experiments of the removal of dyes
Determination of antibacterial activity and live and dead cell analysis
Cell culture and treatment
Statistical analysis
Results and discussions
Photo-removal mechanism of dyes
Re-usability of photocatalysts
Conclusions
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