Photo-degradable salecan/xanthan gum ionic gel induced by iron (III) coordination for organic dye decontamination

Abstract

As dye adsorbents with great potential, polysaccharide-based hydrogels are significantly hampered in practical application owing to intricate preparation methods, low absorption, and bad degradability. Salecan is a water-soluble extracellular polysaccharide with excellent physicochemical and biological properties. Here, salecan and xanthan gum were first used as a dual-precursors system, their mixed solution was crosslinked by Fe3+ to assemble a photo-degradable ionic gel for malachite green (MG) adsorption. Photo-degradation was done using visible light under very mild conditions, which gave rise to gel network dissolution and homogeneous solution formation. Extensive dynamic coordinate interactions between Fe3+ and polysaccharides maintained gel matrix stability and were systematically investigated. The control of water uptake, micro-structure, and rheology can be facilely implemented by tuning salecan/xanthan gum ratios. Furthermore, various parameters such as polysaccharide ratios, pHs, MG concentrations, and contact time affecting adsorption were optimized using batch experiments. Adsorption process accurately adhered to pseudo-second-order kinetic and Langmuir isotherm model, with the maximum adsorption capacity of 463.0 mg/g. Such mechanism implied monolayer chemisorptive characteristics. The gel exhibited satisfactory reusability and was recycled five times without apparent decrease in adsorption capacity. From these results, the photo-degradable Fe3+-induced salecan/xanthan gum ionic gel is an alternative and sustainable absorbent for MG removal.