Sorption behavior of malachite green onto pristine lignin to evaluate the possibility as a dye adsorbent by lignin

Dong-Cheol Seo,Se-Won Kang,Seong-Heon Kim,Ju-Sik Cho,Su-Lim Lee,Jong-Hwan Park,Yong-Bok Lee,Jong-Rok Jeon

doi:10.1186/s13765-019-0444-2

Abstract

The objective of this study was to evaluate the adsorption characteristics of malachite green (MG) on pristine lignin as a dye adsorbent. The adsorption capacity of MG on lignin (31.2 mg/g) was described by Langmuir isotherm and pseudo second order models, and were higher than humic acid (6.4 mg/g). The adsorption of MG by lignin was rapid occurring within 15 min of the reaction, and then equilibrium was reached. The adsorption of MG by lignin based on an intraparticle diffusion model indicated that it was dominated by external boundary. Removal of MG by lignin can be applied at a wide range of pH’s (2–5), and optimal lignin dosage for MG removal was 3 g/L. In addition, the desorption efficiency of MG adsorbed on lignin was highest in methanol + acetic acid (95:5%, v/v) mixture of all solutions tested. The peaks attributed to the hydrogen-bonded stretching vibrations and sulphonyl groups in lignin before MG adsorption, were assigned at about 3400 and 620 cm−1, while the peaks in lignin after MG adsorption were attenuated or reduced. This result indicates that the adsorption of MG by lignin is closely related to the O–H and S–O bonds. Finally, this study suggests that pure lignin, which excludes active processes, can also be used as an adsorbent for dyes. However, in order to utilize the dye-adsorbed lignin repeatedly, further studies will be needed.

Highlights

Research into converting woody biomass into bioethanol and chemical materials has attracted much attention, and has already reached the commercialization stage [1]
Isotherm The adsorption characteristics of malachite green (MG) by lignin and humic acid at different initial dye concentrations is shown in Fig. 1 and Table 1
As the solution concentration of MG exposed to both lignin and humic acid increased, the adsorbed amount progressively increased, whereas it reached an equilibrium at MG concentration of 100 mg/L (Fig. 1a)

Summary

Introduction

Research into converting woody biomass into bioethanol and chemical materials has attracted much attention, and has already reached the commercialization stage [1]. Lignin is an amorphous material with an aromatic structure, which accounts for about 25–35% of woody biomass, the second most abundant natural polymeric substance. Yin et al [7] reported that lignin has a number of functional groups including hydroxyl, methoxyl and carbonyl groups, and can be utilized as a raw material for chemical manufacture through chemical modification techniques such as oxypropylation and epoxidation [8]. Some researchers have found that materials derived from the chemical modification of lignin can be utilized as raw materials for making plastics such

Objectives

Methods

Results