Abstract
P*-Mono- and P*,P*-bidentate phosphorodiamidites containing the (S a )-1,1′-binaphthyl core and 1,3,2-diazaphospholidine rings were synthesized. The use of these compounds in the rhodium-catalyzed asymmetric hydrogenation, as well as in the palladium- and platinum-catalyzed asymmetric alkylation and amination, resulted in the formation of the products with ee of up to 99%.
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