Abstract

Phosphorescence, delayed monomer fluorescence, and delayed excimer fluorescence of 1-chloronaphthalene are readily observable in conventional anionic and cationic micelles. The delayed luminescences are shown to arise predominantly from triplet-triplet annihilation within a single micelle. A kinetic analysis of the data allowed evaluation of the rate constant for intramicellar triplet-triplet annihilation and the rate constant for exit of 1-chloronapthalene from a micelle. 18 references.

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