Abstract

Nanotechnological advances in 2-D nanomaterials (NMs) have recently increased their extent of usage as multifunctional NMs and their embedment in varying polymeric matrices have incorporated enhanced features for multifaceted applications. On the other hand, as a result of inherent flaws in certain 2-D NMs (carbon nanotubes (CNTs), graphene (GN), and so on), the quest for new 2-D NMs with capacity to fill the void caused by these limitations has continually escalated, thereby inducing phosphorene (PN) development, an emerging 2-D NM, similar to GN, and an allotrope of phosphorous (PH). The incorporation of PN within varying polymeric matrices have resulted in the formation of superior PN@polymeric nanoarchitectures applicable in electrochemical energy storage devices (EESD) (supercapacitors, lithium ion batteries (LIBs) along with emerging technologies (sodium ion batteries, lithium–sulfur batteries, and magnesium ion batteries), electronics, photo-thermal gadgets, sensing, optoelectronics, biomedicals, photovoltaic, and so on. Hence, the current elucidation offers insight into the design, development, characterization, and EESD application of PN and PN@polymeric nanoarchitectures. Furthermore, application in energy conversion gadgets and photo-catalysts are elucidated.

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