Abstract
Palladium complexes supported by tridentate phosphido diphosphine ligands (P(o-C6H4PR2)2: 1, R = iPr; 2, R = Ph) have been synthesized, characterized, and tested as catalysts for the electrophilic allylation of aldehydes. The palladium complex 2 resulted in an interesting catalyst for electrophilic allylation in the presence of allyltributyltin, giving good yields under very mild reaction conditions and even in the absence of the solvent.
Published Version
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