Abstract
Rubber compounding with two or more components has been extensively employed to improve various properties. In particular, natural rubber (NR)/ethylene-propylene-diene monomer rubber (EPDM) blends have found use in tire and automotive parts. Diverse fillers have been applied to NR/EPDM blends to enhance their mechanical properties. In this study, a new class of mineral filler, phlogopite, was incorporated into an NR/EPDM blend to examine the mechanical, curing, elastic, and morphological properties of the resulting material. The combination of aminoethylaminopropyltrimethoxysilane (AEAPS) and stearic acid (SA) compatibilized the NR/EPDM/phlogopite composite, further improving various properties. The enhanced properties were compared with those of NR/EPDM/fillers composed of silica or carbon black (CB). Compared with the NR/EPDM/silica composite, the incompatibilized NR/EPDM/phlogopite composite without AEAPS exhibited poorer properties, but NR/EPDM/phlogopite compatibilized by AEAPS and SA showed improved properties. Most properties of the compatibilized NR/EPDM/phlogopite composite were similar to those of the NR/EPDM/CB composite, except for the lower abrasion resistance. The NR/EPDM/phlogopite/AEAPS rubber composite may potentially be used in various applications by replacing expensive fillers, such as CB.
Highlights
Rubbers with high diene contents, such as natural rubber (NR), polybutadiene, nitrile rubber, and styrene-butadiene rubber, exhibit poor outdoor properties [1,2,3,4]
NR/ethylene-propylene-diene monomer rubber (EPDM) rubber blends have been extensively employed in various applications, in tire-related parts [23]
The infiltration of AEAPS solution (AEAPSS) 2 phr into the NR/EPDM/phlogopite elastomeric composites led to compatibilizing effects, thereby increasing the Mooney viscosity
Summary
Rubbers with high diene contents, such as natural rubber (NR), polybutadiene, nitrile rubber, and styrene-butadiene rubber, exhibit poor outdoor properties [1,2,3,4]. NR/EPDM blend systems inevitably require fillers to enhance the mechanical properties, improve processability, add colors, and reduce the cost. CB and silica are the most widely used [20,38] Despite their strong interactions with rubbers, they are relatively expensive, and the application of CB has been hindered owing to its black color [37,38]. Potential fillers such as soybean protein [39], organo-montmorillonite [40], bio-based fibers [41,42], and biochar [43] have been investigated as alternatives. The AEAPS solution (AEAPSS) was composed of AEAPS, DIW, and acetic acid (30:20:50 wt%)
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