Abstract
The crystalline polyamide phase in two representative poly(ether- block-amide) copolymers has been shown to be polymorphic in nature via an analysis by X-ray diffraction and solid-state 13C nuclear magnetic resonance. In both polymers, this phase was found to adopt α and γ structures analogous to those that exist in the corresponding polyamide homopolymers. Furthermore, it has been shown that phase transformation between crystal types is possible using chemical modifications.
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