Abstract

Phase equilibria in the MeCu(O) systems were studied using experimental and calculation procedures. XRD and DTA were used for experimental determination of thermodynamic data. For the calculation of the phase diagrams a mathematical solution of the equations resulting from the condition of thermodynamic equilibria in partially open systems was employed. As a result the series of phase diagrams of the SrOCuO x , BiO 1.5CuO x and BaOCuO x pseudobinary systems for the various partial pressures of oxygen are presented.

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