Abstract

Equilibrium conditions for hydrate formation from binary mixtures of C 2H 6, C 3H 8 and noble gases such as Ar, Kr and Xe were experimentally determined at the temperatures of 273.5, 276.5 and 278.5 K. The binary systems of Xe + C 3H 8, Kr + C 3H 8 and Kr + C 2H 6 mixtures have hydrate azeotropes with pressure minimum points in the isothermal pressure-composition diagrams. Hydrate structural transitions were also observed in the binary systems of Xe + C 3H 8 and Kr + C 2H 6 mixtures.

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