Phase Diagram of Hydrogen in Palladium

Abstract

Hydrogen in palladium, Pd-H(D), is an interesting system because of the highly mobile hydrogen and the presence of a phase boundary below 100 K. Experimentally, however, the nature of this transition has not been established. Historically this transition around 55 to 100 K has been thought to be an order-disorder transition. Such a transition would produce a phase boundary with anomalies at specific hydrogen concentrations corresponding to the specific ordered structures. In order to check this phase boundary we have performed a detailed study of the hydrogen concentration dependence of the specific heat of PdH x over the temperature range from below 0.5 K to above 100 K using PdH x specimens with x up to 0.8753. The measured heat capacity has been analyzed as the sum of contributions due to the lattice specific heat of Pd, the electronic specific heat of PdH x , and the excess contribution caused by hydrogenation of the specimen. The excess specific heat result shows a sharp peak which indicates a phase boundary with transition temperature T 1=55 K to 85 K depending linearly on the hydrogen concentration from x=0.6572 to 0.8753. We do not observe anomalies at specific x values as would be expected for the specific ordered structures.