Abstract

The contribution of hydrogen atoms oscillations in Palladium in pair interaction H–H is calculated. The interpolation formula for an electronic chemical potential of a hydrogen subsystem containing only two energy parameter is obtained. It is shown that the approximation of an mean field for the configuration contribution to a chemical potential with renormalized due to oscillations to energy parameters with allowance for of electronic contribution satisfactorily describes an equilibrium of phases in a system a palladium–hydrogen.

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