Abstract
The statistical associating fluid theory (SAFT) equation of state has been shown to accurately predict the effects of molecular weight, intermolecular association, and compressibility on the phase behavior of mixtures containing solvents, monomers, and polymers. In this paper, we briefly review the physical basis for the SAFT approach and present recent extensions of the equation of state. An advantage of theoretically based equations of state is that the theory can be systematically improved to address weaknesses or to extend the theory to more complex fluid systems. Recent developments beyond SAFT allow us to predict the effects of multiple polar groups on the phase behavior of polar copolymers, model the effects of intramolecular association, and efficiently calculate phase equilibrium for polydisperse polymer solutions. These points are illustrated through comparisons with phase equilibria data for monomers, solvents, and copolymer systems.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
