Abstract
The presence of pharmaceutical micropollutants in water and wastewater is considered a serious environmental issue. To eliminate these pollutants, biodegradation of pharmaceuticals using enzymes such as laccase, is proposed as a green method. In this study, immobilized laccase was used for the removal of two model pharmaceutical compounds, carbamazepine and diclofenac. Polyvinylidene fluoride (PVDF) membrane modified with multi-walled carbon nanotubes (MWCNTs) were synthesized as a tailor-made support for enzyme immobilization. Covalently immobilized laccase from Trametes hirsuta exhibited remarkable activity and activity recovery of 4.47 U/cm2 and 38.31%, respectively. The results also indicated improvement in the operational and thermal stability of the immobilized laccase compared to free laccase. Finally, by using immobilized laccase in a mini-membrane reactor, removal efficiencies of 27% in 48 h and 95% in 4 h were obtained for carbamazepine and diclofenac, respectively. The findings suggest that immobilized laccase on PVDF/MWCNT membranes is a promising catalyst for large-scale water and wastewater treatment which is also compatible with existing treatment facilities.
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