Petrogenesis and U[sbnd]Pb (titanite) age of Cu[sbnd]Ag skarn mineralization in the McKenzie Gulch area, northern New Brunswick, Canada

Abstract

Copper–silver skarn occurrences in the McKenzie Gulch (MG) area are spatially associated with Middle Devonian (386.3 ± 2.3 Ma; UPb zircon) intermediate to felsic dyke swarms. Mineralization occurs as veins and stockwork veinlets, disseminations, patches, and locally as replacement of calc-silicate skarns in argillaceous limestone. Fluid inclusion data from the MG deposit suggest that hydrothermal systems associated with skarn formation evolved from an early magmatic-dominated stage to a late formation water and/or meteoric water-dominated stage. An early prograde endoskarn and exoskarn formed from high temperature (444–865 °C) and high salinity (36–40 wt% CaCl2 + NaCl) fluids, whereas retrograde skarn formed from low temperature (97–257 °C) and low salinity (1–15 wt% NaCl equiv.) fluids. The salinity gap between prograde and retrograde fluids (~ 4-fold dilution) may be due to throttling in the magmatic-hydrothermal system resulting in a pressure regime that alternated between dominantly lithostatic and hydrostatic. The δ34S values of sulfides from the skarn deposit range from +4.6 to +9.1‰. These values are lower than the corresponding δ34S values from the adjacent gold-bearing quartz-calcite-sulfide veins whose values range from +7.9 to +10.0‰. These high positive values suggest that magmatic hydrothermal fluids interacted with and incorporated significant amount of sulfides from sedimentary rocks, which typically have higher δ34S values in the region.Hydrothermal titanites from retrograde skarn ores were successfully dated by laser ablation-inductively coupled plasma-mass spectrometry (LA–ICP–MS) in an effort to constrain the timing of mineralization. These analyses yield weighted mean 206Pb/238U age of 387.2 ± 3.6 Ma, in agreement with 206Pb/238U age of 386.3 ± 2.3 Ma of zircon from associated porphyry dykes. The felsic porphyry dykes spatially associated with CuAg skarn at MG, coupled with fluid inclusion data, provide evidence for magmatic activity coincident with the mineralizing events. In addition, Pb isotope compositions of galena and other sulfides (chalcopyrite, pyrite and pyrrhotite) are compatible with a model linking the skarns with Early to Middle Devonian magmatic activity at depth that eventually interacted with and incorporated significant volumes of sedimentary host rocks. Consequently, the MG CuAg skarn mineralization occurred contemporaneously with the intrusion of porphyry dyke swarms.