Perturbation approach for equation of state for hard-sphere and Lennard–Jones pure fluids

Abstract

In this paper we have established the equation of state (EOS) for liquids. The EOS was established for hard-sphere (HS) fluid along with Lennard–Jones (LJ) fluid incorporating perturbation techniques. The calculations are based on suitable axiomatic functional forms for surface tension S m (r), r ≥ d/2 with intermolecular separation r, as a variable, and m is an arbitrary real number (pole). The results for βP/ρ from the present EOS thus obtained are compared with Percus-Yevick (PY), scaled particle theory (SPT), and Carnahan–Starling (CS). In addition, we have found a simple EOS for the HS fluid in the region which represents the simulation data accurately.