Abstract

Silver crafts wastewater (SCW) typically contains environmentally harmful heavy metals, including Ag, Cu, Mn, and Cr, necessitating treatment before disposal. This study explores a promising solution using silica (SiO2) adsorbents derived from snake fruit peel through acidic activation with HCl concentrations of 2, 4, and 6 M. Qualitative analysis of the adsorbent involved Fourier-transform infrared spectrometer (FTIR) and x-ray fluorescence (XRF) techniques. XRF analysis revealed major compositions of Si (26%) and Cl (71.46%), with minor elements such as Ca (0.91%), P (0.42%), K (0.37%), Fe (0.12%), and others. FTIR analysis indicated the presence of siloxane (Si-O-Si) and silanol (Si-OH) on the adsorbent. The SiO2 adsorbent demonstrated effectiveness in removing heavy metals (Ag, Cu, Mn, and Cr) from SCW, achieving removal percentages of approximately 16.96%, 24.38%, 19.34%, and 9.82%, respectively. This research contributes to the development of an environmentally friendly approach for SCW treatment using silica adsorbents derived from agricultural waste.

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