Performance of GH4169 brazed joint using a new designed nickel-based filler metal via cluster-plus-glue-atom model

Abstract

A novel Ni-Cr-Si-B filler metal with the cluster formula of [Cr-Ni12]B2Cr + [B-Ni8Cr]BSiCr based on the cluster-plus-glue-atom model was designed for vacuum brazing GH4169 alloy. The effect of brazing temperature and brazing time on microstructure and shear strength of GH4169 alloy joints was investigated. The brazed seam was mainly composed of γ-Ni solid solution. (Nb, Ti)-rich phase and (Cr, Nb, Mo)-rich borides distributed in diffusion zones. The diffusion and aggregation of B, Cr, Nb, and Mo resulted in the variation of phase contrast and morphology of borides. Coarse precipitations in the joint brazed at 1240 °C consisted of borides, Laves phase and δ phase. The shear strength of joints was principally dominated by the brittle precipitations in diffusion zone, and the homogenization of microstructure improved the room-temperature shear strength to 820 MPa with the high-temperature shear strength of 627 MPa for the joint brazed at 1240 °C/20 min. The joint fractured in diffusion zone and brazed seam, and the existence of borides and Laves phase in diffusion zone provide the potential origin for crack growth.