Performance assessment of a perovskite solar cell-driven thermionic refrigerator hybrid system

Abstract

To develop a high-performance solar refrigeration technology, a novel refrigeration system composed of a perovskite solar cell (PSC) and a thermionic refrigerator (TIR) is constructed. Based on theories of photovoltaic effect, thermionic emission and non-equilibrium thermodynamics, the coefficient of performance (COP) and refrigerating capacity of the integrated system are mathematically expressed, in which the various irreversible losses are taken into consideration. The integration characteristics and coupling relationships between the PSC and TIR are investigated, and the working voltage regions for the combined operation of the subsystems are determined. Furthermore, the impacts of the area ratio, the work function, the environment temperature, the cold reservoir temperature and the heat transfer coefficient on systemic performance are evaluated in detail. Numerical calculation examples illustrate that the maximum COP and maximum refrigerating capacity of the integrated system are 0.81 and 81.2 W, respectively. Analysis results show that there exist optimal area ratio and work function to optimize the system performance. The present study may offer some fresh perspectives on the evolution of the solar refrigeration system.