Abstract
The intermediate perfluoroalkylated diblock hydrophobic–hydrophilic secondary alcohols ( 9– 11), which were prepared by the reaction of monomethyl ethers of oligomeric ethyleneglycols with 2-[(perfluoroalkyl)methyl]oxiranes ( 7 and 8), resulted in the formation of the title monomers ( 12– 14) by the acylation with methacryloyl chloride. Copolymers of 12– 14 with HEMA and DEGMA prepared under radical conditions display enhanced swelling properties.
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