Abstract

The catalytic behavior of several inexpensive and simple N-heterocyclic organic catalysts in ring-opening polymerization (ROP) of ω-pentadecalactone (PDL) and e-caprolactone (CL) has been studied. The polymerization reactions, carried out in bulk monomer and in toluene solution at 100 °C, identified 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) in combination with benzyl alcohol (BnOH) as initiator as the only active catalyst for the ring-opening polymerization of PDL and for the copolymerization of PDL and CL. The guanidine N-methyl-TBD (MTBD), 1,2,3-triisopropylguanidine, the amidine 1,8-diazabicycloundec-7-ene (DBU), and other N-heterocyclic organic catalysts such as dialkylaminopyridine (DMAP), imidazole, indoles, and N-heterocyclic carbenes (NHC’s) tested in this study proved to be inactive in the ROP of PDL even for the long reaction times. The polymerization mechanism, kinetic studies, temperature, and monomer concentration effects were investigated both in solution and in bulk monomer. The pseudolivin...

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