Abstract
Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
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