Abstract

The terpolymerization of CO, ethylene, and additional olefins varies the properties of polyketones depending on olefins. In this study, monomer candidates for the terpolymerization of polyketones were expanded to alkynes, in addition to olefins. Thermal properties of polyketones were modified by adding aromatic alkynes during Pd‐catalyzed terpolymerization with CO and ethylene. The Tm values of terpolymers were reduced to 192–215°C.

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