Abstract
AbstractA Pd‐catalyzed Mizoroki‐Heck annulation/equivalent aminocarbonylation reaction of alkene‐tethered aryl iodides with nitro compounds is accomplished, providing facile access to diverse carbamoyl‐substituted benzoheterocycles, such as indolin‐2‐ones and 2,3‐dihydrobenzofurans, in moderate to good yields. The cost‐effective Mo(CO)6 complex is discovered to be a solid carbonyl (CO) source and an ideal reducing agent, enabling the efficient production of the desired benzoheterocycles with broad substrate scope tolerance, including both nitroarenes and nitroalkanes under external reductant‐free conditions.
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