Partial black porcelain using wood charcoal as carbon source: Characterization of porcelain body part

Abstract

This paper observes the fabrication of partial black porcelain by carbon diffusion from wood charcoal as a solid carbon source, and the characterization of body at bottom area. The porcelain cup was created by conventional ceramic technique. For second firing step, the cup was set on the wood charcoal pieces contained in a closed refractory container and fired at 1250 °C for 1 h. The traces of carbon compounds at different positions on a cross-section sample were detected by Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Graphitic carbon and Si − O − C were discovered. Furthermore, graphite peak was detected by X-ray diffraction (XRD). This work provides a confirmation of solid diffused carbon from wood charcoal into the porcelain body by scientific techniques.