Abstract
Acetylenic aryl triflates reacted readily with vinyltributyltin, allyltributyltin, 1-(trimethylsilyl)-2-(tributylstannyl)acetylene, and trimethylsilyltributyltin in the presence of a palladium catalyst to produce (Z)-indanylidene and (Z)-tetralinylidene substituted compounds, the stereospecificity of the reactions for the synthesis of these compounds being ≥98%.
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