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https://doi.org/10.1039/c2cc35259a
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Cite Journal: Chemical Communications |  Publication Date: Jan 1, 2012 |
 Citations: 29 |
A palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary stereocenter at the 3-position has been achieved by the reaction of γ-methylidene-δ-valerolactones with alkyl isocyanates. High enantioselectivity has been realized by employing a newly synthesized chiral phosphoramidite ligand.
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