Abstract
More confused: Metalation reactions of [32]heptaphyrins(1.1.1.1.1.1.1) with PdII ions result in a rearrangement to form PdII complexes that contain an N-confused-porphyrin (NCP) framework (see scheme). This rearrangement was also demonstrated for a monozinc(II) heptaphyrin complex with a figure-eight conformation. The occurrence of these transformations shows that NCPs can now be considered a member of the expanded porphyrin family. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Published Version
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