Abstract
AbstractThe palladium‐catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para‐allylated dearomatization products or para‐allylated arenes in satisfactory to good yields. 2‐(Chloromethyl)thiophenes and 2‐(chloromethyl)furans bearing substituents on the 5‐positions also smoothly reacted with allyl pinacolborate, producing the 5‐allylated dearomatization products in satisfactory yields.magnified image
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