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https://doi.org/10.1016/j.tetlet.2016.05.092
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Cite Journal: Tetrahedron Letters |  Publication Date: May 24, 2016 |
 Citations: 31 |
Affiliation: Shanghai Institute of Technology
We developed a method that involved an asymmetric conjugate addition of secondary phosphines to α,β-unsaturated enones bearing β-2-pyridyl substituents catalyzed by a PCP pincer–Pd complex. The technique was established for the preparation of chiral P,N-compounds in excellent enantioselectivity (up to 99% ee) under mild conditions.
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