Abstract

p-Toluenesulfonyl azide (TsN3, CAS: 941-55-9) can be prepared in good yield from the reaction of p-toluenesulfonyl chloride (TsCl) and sodium azide (NaN3) (Scheme [1]).[1] TsN3 is a colorless oil with a melting point of 21–22 ºC and boiling point of 110–115 °C at 0.001mmHg.[2]

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