Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model, and model calculations

Abstract

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago ( Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O 3 and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.