Oxygen vacancy-driven strong metal-support interactions on AuPd/TiO2 catalysts for high-efficient air-oxidation of 5-hydroxymethylfurfural

Abstract

The regulation ofstrong metal-support interactions (SMSI) has emerged as a powerful strategy in boosting catalytic activity and controlling product selectivity. However, directly tuning the metal-supportinteractions in oxide supported metal nanocatalysts remains challenging. Herein, citric acid (CA)‑assisted synthesized TiO2 layer on halloysite nanotubes (HNTs) with varied oxygen vacancies (Ov) concentrations was designed for loading AuPd nanoparticles. SMSI between the AuPd nanoparticles and the TiO2-xCA@HNTs support was successfully induced by adjustable Ov concentrations. The synthesized catalyst was employed for air-oxidation of bio-based 5-hydroxymethylfurfural (HMF) to bioplastic monomer 2,5-furandicarboxylic acid (FDCA) in water. A satisfactory FDCA yield of 98.4 %, accompany with an outstanding FDCA formation rate of 900.9 mmol·g−1·h−1 and an excellent TOF value at 441.2 h−1 was afforded. Based on catalysts characterizations and experimental studies, the catalytic performance was significantly affected by Ov concentrations. The kinetic study showed that the supported gold nanoparticles in alkaline environment had strong aldehyde oxidation activity but weak alcohol oxidation ability. On the contrary, supported palladium nanoparticles were more conducive to alcohol oxidation. This imbalance was overcome by the loading of AuPd nanoparticles, which enhanced the activity for air-oxidation of HMF. Mechanistic studies demonstrated that the stronginteractions between noble metal nanocatalysts and supports were regulated by Ov, which not only increased the adsorption capacity of the substrate and crucial intermediate, but also facilitated the adsorption and activation of molecular oxygen to generate oxygen active species of superoxide radicals. The possible catalytic mechanism for air-oxidation of HMF over Ov-driven SMSI on the obtained catalysts was proposed. This work sheds lights on the design of supported metal catalysts with SMSI for the catalytic upgrading of biomass-derived platform chemicals.