Abstract

Oxygen isotope diffusion coefficient, D *, of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF6428) was measured as a function of p(O2) and temperature. Vacancy diffusion coefficient, D V, was calculated from D * and reported values of oxygen nonstoichiometry, δ. There was little dependence of D V on δ or p(O2) while D V by conductivity relaxation method was reported to drastically decrease with decreasing p(O2) below 10-2 bar. The absolute values of D V in this study were about an order of magnitude larger than those by conductivity relaxation method.

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