Abstract
A new series of oxovanadium(V) 1,2-diolate compounds have been prepared, characterized, and structurally investigated. The reactions of oxovanadium trialkoxides with trans-1,2-cyclohexanediol, (±)-2,3-butanediol, 2R,3R-butanediol, and ethylene glycol produced yellow solid materials. These materials contain two diols for each vanadium presumably in a dimeric arrangement. Solution-state 51 V NMR spectroscopy reveals the presence of complex association and ligand exchange equilibria, necessitating structural characterizations in the solid state. Since single-crystal X-ray diffraction analysis studies were limited as a result of disorder, the materials were characterized by solid-state 51 V and 13 C NMR spectroscopy
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