Abstract
Oxo-bridged dinuclear ruthenium(III) complex [Ru 2(μ-O){η 2( N, N)-bpy} 2{μ-η 1(C),η 2( N, N)-bpy} 2](PF 6) 2 ( 1) with ortho-metalated 2,2′-bipyridine (bpy) was synthesized and characterized by X-ray crystallography. Electrochemical studies revealed that the Ru 2 III,III complex exhibits four reversible or quasi-reversible redox processes due to successive oxidation or reduction of the diruthenium centers.
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