Oxidomolybdenum(VI) complexes with aminoalcohol bis(phenolate) [O,N,O,O′] ligands: Synthesis and catalytic studies

Juuso Hakala,Ari Lehtonen,Reijo Sillanpää

doi:10.1016/j.inoche.2012.03.043

Oxidomolybdenum(VI) complexes with aminoalcohol bis(phenolate) [O,N,O,O′] ligands: Synthesis and catalytic studies

Juuso Hakala, Ari Lehtonen + Show 1 more

https://doi.org/10.1016/j.inoche.2012.03.043

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Journal: Inorganic Chemistry Communications	Publication Date: Apr 9, 2012
Citations: 10

Affiliation: University of Turku, University of Jyväskylä

#Separable Isomers #Oxotransfer Reaction + Show 3 more

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Abstract

Abstract Oxidomolybdenum(VI) complex [MoOCl(Ln)] with a tetradentate O3N-type aminoalcohol bis(phenol) was prepared as two separable isomers. These complexes can catalyse the epoxidation of cis-cyclooctene and sulphoxidation of tolyl methyl sulphide as well as the oxotransfer reaction between PPh3 and DMSO.

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