Abstract
Triphenylarsine dinitrate can be prepared from the dibromide both by metathesis with silver nitrate and by reaction with dinitrogen tetroxide. In contrast to the oxygen bridged compound, (Ph 3SbNO 3) 2O, formed on hydrolysis of the analogous stibine dinitrate, a 1:1 adduct of nitric acid with triphenylarsine oxide results from hydrolysis of triphenylarsine dinitrate. Nitrato-phosphorus compounds did not result from reactions of triphenylphosphine dibromide with silver nitrate, dinitrogen tetroxide or dinitrogen pentoxide.
Published Version
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