Oxidative weathering of pyrite in acidic environments: Data-driven experimental evaluation coupled with Raman hyperspectral imaging

Abstract

This study deals with the identification of the factors that affect pyrite oxidation in acid mine drainage conditions. For this scope, weathering experiments have been carried at laboratory scale based on the design of experiments methodology to evaluate the effect of factors such as major ion concentrations, crystal size, and humic acids presence over the amount of elemental sulfur produced due to the involved weathering reactions. In particular, metal and anionic concentrations in solution were quantified by inductively coupled plasma-atomic emission spectroscopy and ion-chromatography techniques, respectively, whereas the amount of elemental sulfur was quantified with a high-performance liquid chromatography with diode-array detection technique after proper extraction procedure. A partial least squares regression was calculated to establish a quantitative relationship between the considered factors and the amount of elemental sulfur. After evaluation of the model, ferric iron, crystal size and the presence of humic acids were identified as the relevant factors for pyrite oxidation under acidic conditions. In addition, the surface of the samples was characterized by Raman imaging spectroscopy and subsequently analyzed by explorative hyperspectral analysis methods to assess the spatial distribution of the elemental sulfur as the main weathering product, resulting in a homogenous distribution.