Abstract
The stibinidene complex [Cp′(CO) 2Mn] 2SbSPh ( 1 (Cp′ = η 5CH 3C 5H 4) could not be obtained from the reaction of the iodostibinidene complex [Cp′(CO) 2Mn] 2SbI ( 2) with thiophenol. Instead, 2 reacts with thiophenol to give the product of an oxidative addition process, Cp′(CO) 2MnSb(SPh) 3 ( 3) and the radical complex, Cp′(CO) 2MnSPh ( 4). The compounds 3 and 4 could also be obtained from the reaction of Cp′(CO) 2MnTHF with Sb(SPh) 3. The structure of 3 has been determined by X-ray crystallography.
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call