Abstract

A duplex composite coating consisting of electrodeposited SiO 2 interlayer and glass-ceramic coating was fabricated on TiAl alloy. The oxidation behavior of the composite coating was studied in air at 1000 °C. The composition, morphology, and microstructure of the oxide scale were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive spectroscopy (EDS). Results showed that the composite coating exhibited outstanding resistance against high temperature oxidation. After 100 h oxidation, no scale spallation was observed and the weight gain was only 1.16 mg cm −2 . The inward diffusion of oxygen and outward diffusion of Ti were efficiently prevented. A continuous and adherent Al 2 O 3 layer was formed at the coating/substrate interface. The electrodeposited SiO 2 interlayer could improve the adhesion between the substrate and glass-ceramic coating. • Glass-ceramic coating and SiO 2 interlayer were fabricated on TiAl alloy. • SiO 2 interlayer can dissolve into the glass-ceramic coating and reduce its mobility. • The adhesion property of the glass-ceramic coating was enhanced. • The formation of nitride at the coating/substrate interface was suppressed.

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