Abstract

Studies of the complete oxidation of methane on a Pt electrode-catalyst in the cell with a solid proton-conducting electrolyte (CH4 + O2, Pt ¦ SrCe0.92Dy0.08O3 ¦ Pt, H2O + N2) were carried out. The non-Faradaic effect of electrochemical hydrogen pumping on the rate of methane oxidation has been demonstrated. The induced change in the reaction rate at anodic polarization of a Pt electrode-catalyst was over two orders of magnitude higher than the rate of hydrogen pumping from the reaction zone through the electrolyte.

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