Abstract
1. Under the conditions of low-temperature oxidation of cyclohexene, cobalt(II) molybdate catalyzes the epoxidation of the double bond by the cyclohexene hydroperoxide which is formed. 2. The catalytic function of manganese(II) molybdate is connected with radical breakdown of hydroperoxide on its surface. Parallel with this radical breakdown, molecular decomposition of hydroperoxide takes place on the surface with the formation of cyclohexanone. As well as taking part in chain initiation, manganese molybdate also participates in the radical breakdown stage. 3. The catalytic function of silver molbydate is associated with mutual activated absorption of oxygen and hydroperoxide on its surface. Formation of hydroperoxide takes place in the surface layers without giving rise to radicals in the liquid phase.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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