Abstract
The oxidation of carbon derived from phenolic resin and heat-treated at temperatures ranging from 1000 to 2400°C for 1 hr was studied in a flowing oxygen atmosphere at temperatures between 424 and 692°C. The heat-treatment alters the crystallite size, L c , from 10.7 to 21.4 Å; the interlayer spacing, d 002, from 3.74 to 3.52 Å and the surface area from 0.22 to 1.34 m 2/g. L a L c ratio ranges from 1.62 to 2.22 and appears to be independent of heat treatment temperature and oxidation level. The surface area of the carbon and its change with oxidation were found to be sensitive to the heat treatment process. Heat treatments at 1000 and 1400°C produce carbon with surface area which increases by nearly two orders of magnitude after 10% oxidation. The oxidation rate decreases with increasing heat treatment temperature with the largest change between 1000 and 1400°C. Samples heat-treated at different temperatures give slightly different activation energies with an average value of 41.5 kcal/mole.
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