Abstract
The oxidation of allyl alcohol by alkaline species of periodate, H2IO63−, was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm−3 alkali solution. The active species of the catalyst was found to be PdCl+. A mechanism involving the interaction of the catalyst and substrate in prior equilibria leading to the formation of a π-complex is proposed and the rate is derived. © 1998 John Wiley & Sons, Ltd.
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