Abstract

Underground storage is the most ecologically clean and economical method for extended storage of natural gas, crude oil, and petroleum products. Such storage reservoirs are created in stable rock (granites, gneisses, limestone, etc.), rock salt deposits, clays, abandoned mines, and permafrost formations. In this investigation of the influence of rock salt deposits on the oxidation of hydrocarbons (summer-grade straight-run diesel fuel L and automotive gasoline A-76 [unleaded, low-octane]), the authors carried out a kinetic study of hydroperoxide accumulation during the oxidation of these fuels after contact with a saturated solution of rock salt (brine). The experiments were performed in a bubbler-type unit with various ratios of brine to fuel.

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